Dissociative Recombination: Theory, Experiment, and Applications (Softcover Reprint of the Original

InMay1988, theFirstInternationalConferenceonDissociativeRecombination: Theory, ExperimentandApplicationswasheldatChateauLakeLouise, Alberta, Canada. Thismeeting gaveaconsiderableimpetustothissubject, whichisofparticularinterestforalargevarietyof fieldsincludinginterstellarclouds, planetaryatmospheres, gaslasers, plasmaprocessing, ion sourcesandthermonuclearplasmas. Sincethen, indeed, severalcollaborationswereinitiated betweenexperimentalistsworkingwithdifferenttechniques, betweentheoreticiansdealingwith molecularstructureononehandanddynamicsontheotherhandandalsobetween experimentalistsandtheoreticians. Duringthelastfouryears, therefore, alargenumberof studieswerecarriedoutandraisedanewsetofquestions. Moreparticularly, theresultsthat wereobtainedconcerningcontroversialspeciessuchasH!andHeir, castingsomedoubton theverymechanismsbywhichdissociativerecombinationproceeds. The Second International Conference on Dissociative Recombination: Theory, ExperimentandApplications heldat"I'AbbayedeSaintJacutdelaMer", Brittany, France, May3-8,1992, camethereforeattherighttimetosurveythecurrentstateofthesubject. The symposiumbroughttogetherleadinginvestigatorsinthefieldsofmolecularionrecombination research, atomicandmoleculartheoryandexperiment, plasmasphysics, astrochemistryand aeronomy. Speakerspresentedtalksreviewingtheirownworkandthesewerefollowedby livelydiscussionsessions. Freetimeperiodsallowedparticipantstodiscoveranenchanting peninsulaofNorthBrittanywhilepursuingstimulatingscientificdiscussions. Thepapersinthis volumearebasedonthesetalksandfurtherdiscussions, withtheexceptionofcontributions fromT. AmanoandB. M. McLaughlinwhowereunabletoattend. Alistofparticipantsas wellasasouvenirgroupphotoisgivenattheendofthebook. WeareindebtedtoNATOforitsfinancialsupportwhichcontributedtothegreat successofthissecondmeeting. TheUniversityofRennesIandtheBalzerscompanyarealso acknowledgedfortheiradditionalsupportManythankstothewholestaffoftheabbeyforits kindnessandeffortsinprovidinguswithapropitiousenvironmentforsuchaworkshop. We arealsogratefultoL. Caubetforhervaluableadministrativeassistanceduringthepreparation ofthemeeting. Finallyaspecialmentionmustbegiventoallthesessionchairpersonsfortheir skillinorchestratingthediscussions. Lookingforwardtoattendingthethirdmeeting. TheEditors Bertrand R. Rowe J. Bria/l A. Mitchell Andre Callosa DepartementdePhysique DepartmentofPhysics DepartementdePhysique AtomiqueetMoleculaire TheUniversityofWesternOntario AtomiqueetMoleculaire UniversitedeRennesI London, Canada, N6A3K7 UniversitedeRennesI CampusdeBeaulieu CampusdeBeaulieu 35042RennesCedex, 35042RennesCedex, France France v CONTENTS ORALCONTRIBUTIONS PolyatomicIonDissociativeRecombination . 1 D. R. Bates RecentDevelopmentsandPerspectivesintheTreatmentofDissociative RecombinationandRelatedProcesses. . . . . . . . . . . . . . . . . . . . . . . . . . . 11 A. Giusti-Suzor, I. F Schneider, and 0. Dulieu CharacteristicsofSuperexcitedStatesofMoleculesandMQDTStudiesofNO+ DissociativeRecombination. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25 H. Sun, K. Nakashima, and H. Nakamura CalculationsforAr +Xe*andArXe+ +e 35 A. P. Hickman, DL Huestis, and R. P. Saxon Electron-IonContinuum-ContinuumMixinginDissociativeRecombination 47 s. L. Guberman ATheoreticalStudyoftheHCO+andHCS+ElectronicDissociativeRecombinations. . 59 D. Talbi, and Y Ellinger DissociativeRecombinationofCH; SomeBasicInformationfromElectronic 2 StructureCalculat